Ru(ii)–Re(i) binuclear photocatalysts connected by –CH2XCH2– (X = O, S, CH2) for CO2 reduction† †Electronic supplementary information (ESI) available: Stern–Volmer plots of the dyad; UV-vis spectra of the OERs of Ru and Re; UV-vis spectral changes during the photocatalytic reaction; ESI-MS spectrum of the SEC peak at 36.1 min after the 120 min photocatalytic reaction using Ru(CH2OCH2)Re; IR spectral change by the formation of Ru(CH2OCH2)Re(CO)3(X) (X = –OC2H4N(C2H4OH)2 or –OC(O)OC2H4N(C2H4OH)2); Stern–Volmer plots for Ru(CH2OCH2)Re(CO)3(X) (X = –OC(O)OC2H4N(C2H4OH)2); changes of SEC chromatograms, ESI-MS spectra, and IR spectra during the photocatalytic reaction using Ru(CH2CH2CH2)Re; changes of a ESI-MS spectrum after the photocatalytic reaction; ESI-MS spectra of the SEC peak at 36.5 min and 37.8 min after the 120 min photocatalytic reaction using Ru(CH2SCH2)Re. See DOI: 10.1039/c4sc03710c
نویسندگان
چکیده
Department of Chemistry, Graduate Sch Institute of Technology, 2-12-1-NE1, O-o Japan. E-mail: [email protected] CREST, Japan Science and Technology Agen 322-0012, Japan National Institute of Advanced Industrial Tsukuba, Ibaraki 305-8569, Japan † Electronic supplementary information (E dyad; UV-vis spectra of the OERs of Ru and photocatalytic reaction; ESI-MS spectrum o min photocatalytic reaction using Ru(CH formation of Ru(CH2OCH2)Re(CO)3(X) OC2H4N(C2H4OH)2); Stern–Volmer plots OC(O)OC2H4N(C2H4OH)2); changes of and IR spectra during the photocatalyt changes of a ESI-MS spectrum aer the p of the SEC peak at 36.5 min and 37.8 reaction using Ru(CH2SCH2)Re. See DOI: Cite this: Chem. Sci., 2015, 6, 3003
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عنوان ژورنال:
دوره 6 شماره
صفحات -
تاریخ انتشار 2015